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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Communication | Special issue | Vol 54, No. 2, 2001, pp.611-614
Published online, 1st January, 1970■ 1,3-Dipolar Cycloaddition of 1-Phenylpropa-1,2-diene with Pyridinium Dicyanomethylides: 1-Phenylpropa-1,2-diene as a Synthetic Equivalent of 1-Phenylpropyne
Published online, 1st January, 1970
DOI: 10.3987/COM-00-S(I)92
■ 1,3-Dipolar Cycloaddition of 1-Phenylpropa-1,2-diene with Pyridinium Dicyanomethylides: 1-Phenylpropa-1,2-diene as a Synthetic Equivalent of 1-Phenylpropyne
Kiyoshi Matsumoto,* Naoki Tanaka, Takane Uchida, Yukio Ikemi, Naoto Hayashi, Kinuyo Aoyama, and Akikazu Kakehi
*Graduate School of Human and Environmental Studies, Kyoto University, Kyoto 606-8501, Japan
Abstract
Pyridinium dicyanomethylides (1) underwent 1, 3-dipolar cycloaddition with 1-phenyl-propa-1,2-diene (2) to give a mixture of 3-cyano-2-methyl-1-phenylindolizines (4) and 3-cyano-1-methyl-2-phenylindolizines (5), accompanied by dehydrocyanation and 1, 3-sigmatropic hydrogen shift.
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