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Paper | Regular issue | Vol 53, No. 8, 2000, pp.1783-1788
Published online, 1st January, 1970
DOI: 10.3987/COM-00-8945
Benzotriazole-mediated [1,2]-Wittig Rearrangement. The Preparation of Homoalcohols from Ethers

Alan R. Katritzky* and Yunfeng Fang

*Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, U.S.A.

Abstract

α-(Benzotriazol-1-yl)alkyl benzyl ethers (6a-e) undergo [1,2]-Wittig rearrangement upon treatment with 2 equiv of organolithium reagents.