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Paper | Regular issue | Vol 53, No. 8, 2000, pp.1737-1744
Published online, 1st January, 1970
DOI: 10.3987/COM-00-8936
Synthesis and Structural Characterization of Palladium(II) Complex with (L)-3-Acetyl-5-benzyl-1-phenyl-4,5-dihydro-1,2,4-triazin-6-one Oxime. Part II

Ahmad S. Abushamleh, Mustafa M. El-Abadelah,* and Cäcilia M. Mössmer

*Chemistry Department, Faculty of Science, University of Jordan, Amman 11942, Jordan


The synthesis and structural properties of the four-coordinate Pd(L)2 (4), where L is chiral 3-acetyl-5-benzyl-1-phenyl-4,5-dihydro-1,2,4-triazin-6-one oxime, (2), are described. Deep-red needles of 4 crystallize in the hexagonal space group P61. The crystallographic data reveal that the two oxime ligands are not symmetrically coordinated to Pd(II) ion, and the 4N-donor set comprises both oxime nitrogens, an amidrazone nitrogen and a hydrazone nitrogen. 1H-, 13C-NMR and FD-MS spectral data of 4 are consistent with its X-Ray molecular structure.