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Communication | Regular issue | Vol 53, No. 7, 2000, pp.1485-1488
Published online, 1st January, 1970
DOI: 10.3987/COM-00-8920
Palladium-catalyzed Asymmetric Allylic Alkylation Using Chiral P,N-Ligands

Takashi Mino,* Youichi Tanaka, Masami Sakamoto, and Tsutomu Fujita

*Department of Materials Technology, Faculty of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan


Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (8) with a dimethyl malonate-BSA-LiOAc system has been successfully carried out in the presence of new chiral P,N-ligands 5 in good yields with good enan-tioselectives (up to 83% ee).