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Published online: 16th April, 2020

Communication | Special issue | Prepress
DOI: 10.3987/COM-20-S(K)4
Synthetic Studies on Densanins: Stereoselective Construction of A Pyrrolidine Ring Containing a Quaternary Carbon

Kyosuke Ueda and Satoshi Yokoshima*

*Graduate School of Pharmaceutical Sciences, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601, Japan

Abstract

We disclose our synthetic studies on densanins, which feature the stereoselective cycloaddition of a cycloheptenone and an azomethine ylide to construct a pyrrolidine ring containing a quaternary carbon

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Published online: 16th March, 2020

Communication | Special issue | Prepress
DOI: 10.3987/COM-20-S(K)2
5-Arylidenetetronate as A Versatile Electrophore for Pi-Extended Electron Acceptors

Yuki Hayashi, Yusuke Ishigaki, Jérémy Merad, Takanori Suzuki,* and Maurice Médebielle*

*Department of Chemistry, Faculty of Science, Hokkaido University, Kita 10 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan

Abstract

Bis[4-methoxy-5-methylenefuran-2(5H)-one]-type electron acceptors with anthracene-9,10-diyl and thiophene-2,5-diyl spacer were prepared by one-pot condensation of methyl tetronate with the corresponding dialdehydes. They undergo reversible electrochemical reduction, thus showing the potential utility of 5-arylidenetetronate as an electrophore for developing novel electron acceptors.

FREE:Supporting Info. (420KB)PDF (864KB)
62 data found. 61 - 62 listedFirst Previous